If the plan document allows, you can always favor one HCE over another. Plans that cover only HCEs automatically pass testing.
As Truphao points out though you will still make TH minimums if the plan is top-heavy. So in your example, of the owner getting max everyone else getting 0 is fine until your plan becomes top-heavy which could be immediately if its a first year plan with no other money in it, could be never if there is a 401(k) component and you have enough non-key HCEs contributing enough to the plan to keep it below 60%.
And while you say this is a PS, you still need to look out for 401(a)(26) if it's a DB plan or DB/DC combo plan.